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Encyclopedia > Valence shell

The valence shell is the outermost shell of an atom, which contains the electrons most likely to account for the nature of any reactions involving the atom and of the bonding interactions it has with other atoms. Electrons in the valence shell are referred to as valence electrons. The chemist Gilbert Newton Lewis was responsible for much of the early development of the theory of the participation of valence shell electrons in chemical bonding. Linus Pauling later generalized and extended the theory while applying insights from quantum mechanics.

In a noble gas, an atom tends to have 8 electrons in its outer shell (except helium, which is only able to fill its shell with 2 electrons). This serves as the model for the octet rule which is mostly applicable to main group elements of the second and third periods. In terms of atomic orbitals, the electrons in the valence shell are distributed 2 in the single s orbital and 2 each in the three p orbitals.

For organometallic compounds containing transition metals, the valence shell consists of electrons in these s and p orbitals, as well as up to 10 additional electrons, distributed as 2 into each of 5 d orbitals, to make a total of 18 electrons in a complete valence shell for such a compound. This is referred to as the eighteen electron rule.

  Results from FactBites:
The Valence Shell (0 words)
When the valence electron in any atom gains sufficient energy from some outside force, it can break away from the parent atom and become what is called a free electron.
Atoms with few electrons in their valence shell tend to have more free electrons since these valence electrons are more loosely bound to the nucleus.
The valence shell is the outer shell of the atom.
valence, in chemistry. The Columbia Encyclopedia, Sixth Edition. 2001-05 (545 words)
The valence of an atom is determined by the number of electrons in the outermost, or valence, shell.
The valence of many elements is determined from their ability to combine with hydrogen or to replace it in compounds.
Atoms are assigned numbers, called valence numbers, oxidation numbers, or oxidation states, which range in value from -4 through 0 to +7 and describe the combining behavior of the atoms in chemical reactions, particularly oxidation-reduction reactions (see oxidation and reduction).
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