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Encyclopedia > Glycol
Properties

General

Name Ethane-1,2-diol
Chemical formula HOCH2CH2OH
Formula weight 62.07 amu
Synonyms Ethylene Glycol
CAS number 107-21-1

Phase behavior

Melting point 260.2 K (-12.9°C)
Boiling point 470.4 K (197.3°C)
Thermal decomposition ? K (?°C)
Triple point 256 K (-17°C)
? bar
Critical point 720 K (447°C)
82 bar
ΔfusH 9.9 kJ/mol
ΔfusS 38.2 J/mol·K
ΔvapH 65.6 kJ/mol
Solubility Miscible with water.

Liquid properties

ΔfH0liquid -460 kJ/mol
S0liquid 166.9 J/mol·K
Cp 149.5 J/mol·K
Density 1.1132 ×103 kg/m3

Gas properties

ΔfH0gas -394.4 kJ/mol
S0gas 311.8 J/mol·K
Cp 78 J/mol·K

Safety

Acute effects Nausea, vomiting. CNS paralysis. Kidney damage.
Chronic effects Kidney damage
Flash point 111°C
Autoignition temperature 410°C
Explosive limits 1.8-12.8%

More info

Properties NIST WebBook (http://webbook.nist.gov/cgi/cbook.cgi?ID=&Units=SI)
MSDS Hazardous Chemical Database (http://ull.chemistry.uakron.edu/erd/chemicals1/8/7680.html)

SI units were used where possible. Unless otherwise stated, standard conditions were used.


Disclaimer and references

Ethylene glycol (IUPAC name:ethane-1,2-diol) is a chemical compound widely used as an automotive antifreeze (coolant). In its pure form, it is a odorless, colorless, syrupy liquid with a sweet taste. Ethylene glycol is toxic, and its accidental ingestion should be considered a medical emergency.

Contents

History

Ethylene glycol was first prepared in 1859 by the French chemist Charles Wurtz. It was produced on a small scale during World War I as a coolant and as an ingredient in explosives. Widespread industrial production began in 1937, when its precursor ethylene oxide became cheaply available.


When first introduced it created a minor revolution in aircraft design because when used in place of water as a radiator coolant, its higher boiling point allowed for smaller radiators operating at higher temperatures. Prior to the widespead availability of ethylene glycol, many aircraft manufacturers tried to use evaporative cooling systems which used water at high pressure. Invariably these proved to be rather unreliable and easily damaged in combat because they took up large amounts of room on the plane, where they were easily hit by gunfire.


Production

Ethylene glycol is produced from ethylene, via the intermediate ethylene oxide. Ethylene oxide reacts with water to produce ethylene glycol according to the chemical equation

C2H4O + H2O → HOCH2CH2OH

This reaction can be catalyzed by either acids or bases, or can occur at neutral pH under elevated temperatures. The highest yields of ethylene glycol occur at acidic or neutral pH, with a large excess of water present. Under these conditions, ethylene glycol yields of 90% can be achieved. The major byproducts are the ethylene glycol oligomers diethylene glycol, triethylene glycol, and tetraethylene glycol. 2


Uses

The major use of ethylene glycol is as an engine coolant and antifreeze. Due to its low freezing point, it has also been used as a deicing fluid for windshields and jet engines. Ethylene glycol has become increasingly important in the plastics industry for the manufacture of polyester fibers and resins, including polyethylene terephthalate, which is used to make plastic bottles for soft drinks. The antifreeze capabilities of ethylene glycol have made it an important component of vitrification mixtures for low-temperature preservation of biological tissues and organs.


Minor uses of ethylene glycol include the manufacture of capacitors and as a chemical intermediate in the manufacture of 1,4-dioxane.


Ethlyene glycol's high boiling point and affinity for water makes it an ideal dehydrator for natural gas production. In the field, excess water vapor is usually removed by glycol dehydration. Glycol flows down from the top of a tower and meets a rising mixture of water vapor and hydrocarbon gases from the bottom. The glycol chemically removes the water vapor, allowing dry gas to exit from the top of the tower. The glycol and water are separated, and the glycol cycles back through the tower.


Ethylene glycol is also used in vaccines.


Safety

The major danger from ethylene glycol is from its ingestion. Due to its sweet taste, children and animals will sometimes consume large quantities of it if given access to antifreeze. Symptoms of ethylene glycol poisoning follow a three-step progression. Initially, victims may appear to be intoxicated, exhibiting symptoms such as dizziness, slurred speech, and confusion. Over time, the body metabolizes ethylene glycol into another toxin, oxalic acid. Buildup of this substance results in irregularities in the victim's heartbeat and breathing. In the final stage, the victim suffers kidney failure.


Victims of ethylene glycol poisoning who are still conscious may be given milk or water to drink to delay the effects of the poison. In any case, medical attention should be sought immediately. Ethylene glycol doses as small as 30 milliliters (2 tablespoons) can be lethal to adults.


Due to its toxicity, the substance has been in the news at least at two times:


See also:silver fire


  Results from FactBites:
 
Diethylene Glycol (DEG) (724 words)
Polyethylene glycols and polypropylene glycols are sometimes called polyglycols which are derived by polymerization of ethylene oxide and propylene oxide respectively.
Diethylene glycol (DEG) is derived as a co-product with ethylene glycol and triethylene glycol.
Glycols, having high boiling point and affinity for water, are employed as liquid desiccant for the dehydration of natural gas.
Ethers glycol : toxicologie, prevention et controle avec INRS (644 words)
La famille des éthers de glycol se compose de 80 substances chimiques, différentes quant à leurs caractéristiques, qui entrent dans la composition de nombreux produits.
Chaque éther de glycol possède des caractéristiques toxicologiques propres et certains dérivés ont une toxicité sur la reproduction mise en évidence dans des essais chez le rongeur, susceptible d'entraîner un risque pour l'homme ; les composés potentiellement dangereux sont de plus en plus substitués et les mesures réglementaires ont permis de réduire leur utilisation.
Document sur l'ethers de glycol issu de de la base de données Métropol, qui constitue un recueil de techniques de prélèvement et d'analyse des polluants présents dans l'air des locaux de travail.
  More results at FactBites »

 
 

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